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Benzyl bromide

CAS No.100-39-0
Chemical Name:Benzyl bromide
Synonyms:cyclite;ai3-15300;Benzybromide;-Bromotoluene;Bromo Thluene;1-Bromotoluene;α-bromotoluene;A-BROMOTOLUENE;BENZYL BROMIDE;à-bromotoluene
CBNumber:CB6761035
Molecular Formula:C7H7Br
Formula Weight:171.03
MOL File:100-39-0.mol
Benzyl bromide Property
mp : -3 °C
bp : 198-199 °C(lit.)
density : 1.44 g/mL at 20 °C
vapor density : 5.8 (vs air)
refractive index : n20/D 1.575(lit.)
Fp : 188 °F
storage temp. : Store at RT.
Sensitive : Moisture Sensitive/Light Sensitive
Merck : 14,1128
BRN : 385801
Stability:: Stable. Combustible. Incompatible with strong oxidizing agents.
CAS DataBase Reference: 100-39-0(CAS DataBase Reference)
NIST Chemistry Reference: Benzene, (bromomethyl)-(100-39-0)
EPA Substance Registry System: Benzene, (bromomethyl)-(100-39-0)
Safety
Hazard Codes : Xi
Risk Statements : 36/37/38
Safety Statements : 39-2
RIDADR : UN 1737 6.1/PG 2
WGK Germany : 2
RTECS : XS7965000
F : 9-19-21
HazardClass : 6.1
PackingGroup : II
Hazardous Substances Data: 100-39-0(Hazardous Substances Data)

Benzyl bromide Chemical Properties,Usage,Production

Chemical Properties
Clear light amber liquid
General Description
A colorless liquid with an agreeable odor. Toxic by inhalation and by skin absorption. Benzyl bromide is slightly soluble in water and denser than water (density 1.44 g / cm3 (Aldrich)). A lachrymator. Corrosive to metals and tissue.
Air & Water Reactions
Sensitive to exposure to light and moisture. Slightly soluble in water.
Reactivity Profile
Benzyl bromide reacts with water, alcohols, common metals (except nickel and lead), bases, amines and oxidizing agents. . Benzyl bromide stored over activated 4A molecular sieve burst a bottle due to condensation-polymerization reaction with generation of HBr gas, [Chem. Eng. News, 1979, 57(12), 74].
Health Hazard
Inhalation causes irritation of nose and throat; severe exposure may cause pulmonary edema. Vapors cause severe eye irritation; liquid can burn eyes. Skin contact causes irritation. Ingestion causes irritation of mouth and stomach.
Benzyl bromide Preparation Products And Raw materials
Raw materials
Preparation Products
2-(Boc-aminomethyl)-piperidine (S)-(-)-N-Benzyl-1-phenylethylamine Diethyl benzylmalonate 1-BENZYL-1,4-DIAZEPANE Candesartan 2-Methyl-1-phenyl-2-propanol 4-Amino-1-benzylpiperidine O-(2-MethoxyEthoxy)BenzeneSulfonamide 2-(4-BENZYLOXYPHENYL)ETHANOL N-(4-(Benzyloxy)benzylidene)-4-fluoroaniline CYCLOPROTHRIN Benzyldimethylhexadecylammonium chloride Cinosulfuron 3,5-Dibenzyloxybenzyl alcohol 4-BENZYLOXY-3-METHOXYBENZALDEHYDE trans-2,5-Dimethylpiperazine Sulindac 4-(Boc-Aminomethyl)piperidine TERBUTALINE SULFATE 7-Hydroxyindole 4-Benzyloxybenzeneboronic acid 3-Benzyloxybenzaldehyde 3,5-BIS(BENZYLOXY)BENZYL BROMIDE 1-BENZYL-2-IMIDAZOLECARBOXYLIC ACID Indobufen 4-BENZYLOXYANILINE 1,3,5-Benzenetricarboxaldehyde Anagrelide Butenafine hydrochloride 6-CHLORO-1H-PYRROLO[2,3-B]PYRIDINE Benzyldodecyldimethylammonium bromide 5-Hydroxyindole N-BOC-O-Benzyl-L-serine 2-Hydroxydiphenylmethane BOC-3-IODO-D-ALANINE BENZYL ESTER 3-METHYLADENINE (R)-(-)-Benzyl glycidyl ether 4-METHYL-1-PHENYL-2-PENTANOL CROCONAZOLE alpha-[4-[2-(diethylamino)ethoxy]phenyl]-alpha-phenylphenethyl alcohol
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