| Product Identification | Back to Contents | 【Product Name】
Benzene phosphorous oxydichloride | 【Synonyms】
Benzenephosphonic dichloride
Dichlorophenylphosphine oxide
Dichlorophosphorylbenzene
Phenyldichlorophosphine oxide
Phenylphosphonic acid dichloride
Phenylphosphonyl dichloride | 【CAS】
824-72-6 | 【Formula】
C6H5Cl2OP | 【Molecular Weight】
194.99 | 【EINECS】
212-534-3 | 【Beilstein/Gmelin】
1072240 | 【Beilstein Reference】
4-16-00-01074 | 【EC Class】
irritant |
| Physical and Chemical Properties | Back to Contents | 【Appearance】
Clear yellow liquid. Pungent odor. | 【Solubility in water】
Insoluble | 【Melting Point】
1 | 【Boiling Point】
258 | 【Vapor Pressure】
0.02 (25 C) | 【Density】
1.4101 g/cm3 (20 C) | 【Partition Coefficient】
2.01 | 【Heat Of Vaporization】
47.6 kJ/mol | 【Vapor Density】
6.72 | 【Refractive Index】
1.5596 (25 C) |
| First Aid Measures | Back to Contents | 【Ingestion】
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. | 【Inhalation】
Get medical aid immediately. Remove from exposure to fresh air immediately. Do not use mouth-to-mouth respiration if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. | 【Skin】
Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes. | 【Eyes】
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes). |
| Handling and Storage | Back to Contents | 【Storage】
Keep container closed when not in use. Corrosives area. Store protected from moisture. Store in a cool, dry area away from incompatible substances. | 【Handling】
Wash thoroughly after handling. Keep container tightly closed. Do not get on skin or in eyes. Do not ingest or inhale. Use with adequate ventilation. Use and store under nitrogen. Do not allow contact with water. Use only in a chemical fume hood. Discard contaminated shoes. Do not breathe vapors. |
| Hazards Identification | Back to Contents | 【Inhalation】
Causes chemical burns to the respiratory tract. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. Aspiration may lead to pulmonary edema. May cause systemic effects. Inhalation may produce burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. | 【Skin】
Causes skin burns. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color. | 【Eyes】
Causes eye burns. May cause chemical conjunctivitis and corneal damage. | 【Ingestion】
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. May cause systemic effects. | 【Hazards】
When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards. | 【EC Risk Phrase】
R 14 34 37 | 【EC Safety Phrase】
S 26 36/37/39 45 | 【UN (DOT)】
3265 |
| Exposure Controls/Personal Protection | Back to Contents | 【Personal Protection】
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. | 【Respirators】
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. | 【Exposure Effects】
Effects may be delayed. |
| Fire Fighting Measures | Back to Contents | 【Flash Point】
110 | 【Fire Fighting】
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Water hydrolyzes material liberating acidic gas which in contact with metal surfaces can generate flammable and/or explosive hydrogen gas. Extinguishing media: DO NOT USE WATER! Use dry chemical, carbon dioxide, or appropriate foam. | 【Fire Potential】
Combustible material: may burn but does not ignite readily. |
| Accidental Release Measures | Back to Contents | 【Small spills/leaks】
Clean up spills immediately, using the appropriate protective equipment. Absorb spill using an absorbent, non-combustible material such as earth, sand, or vermiculite. Provide ventilation. Do not get water inside containers. |
| Stability and Reactivity | Back to Contents | 【Disposal Code】
24 | 【Stability】
Stable under normal shipping and handling conditions. However, may decompose if exposed to moist air or water. | 【Incompatibilities】
Strong oxidizing agents, strong bases, water. | 【Decomposition】
Hydrogen chloride, phosphine, carbon monoxide, oxides of phosphorus, carbon dioxide. | 【Combustion Products】
Fire may produce irritating, corrosive and/or toxic gases. |
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| Company Name: | J & K SCIENTIFIC LTD. |
| Tel: | 400-666-7788 +86-10-82848833 |
| Fax: | +86-10-82849933 |
| WebSite: | www.jkchemical.com |
| Company Name: | Meryer (Shanghai) Chemical Technology Co., Ltd. |
| Tel: | +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-59487313(Beijing) |
| Fax: | +86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) |
| WebSite: | www.meryer.com |
| Company Name: | Alfa Aesar |
| Tel: | 400-610-6006; 021-67582000 |
| Fax: | 021-67582001/03/05 |
| WebSite: | www.alfachina.cn |
| Company Name: | BeiJing Hwrk Chemicals Limted |
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| Fax: | 010-87653215 0757-86311057 021-55236763 |
| WebSite: | www.hwrkchemical.com |
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