ChemicalBook >>Tosyl chloride>>4-Toluene sulfochloride(98-59-9)

4-Toluene sulfochloride(98-59-9)

4-Toluene sulfochloride(98-59-9)
Product IdentificationBack to Contents
【Product Name】

4-Toluene sulfochloride
【Synonyms】

4-Methylbenzenesulfonyl chloride
p-Tolylsulfonyl chloride
p-Tosyl chloride
【CAS】

98-59-9
【Formula】

C7H7ClO2S
【Molecular Weight】

190.65
【EINECS】

202-684-8
【Merck】

12,9672
【Beilstein/Gmelin】

607898
【Beilstein Reference】

4-11-00-00375
【EC Class】

corrosive
Physical and Chemical PropertiesBack to Contents
【Appearance】

A white to gray powdered solid with a distinctive odor.
【Solubility in water】

Insoluble
【Melting Point】

67
【Boiling Point】

265
【Vapor Pressure】

0.015 (25 C)
【Density】

1.49 g/cm3
【Partition Coefficient】

2.45
【Heat Of Vaporization】

48.3 kJ/mol
【Usage】

Organic synthesis.
【Vapor Density】

1.33
First Aid MeasuresBack to Contents
【Ingestion】

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
【Skin】

Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and StorageBack to Contents
【Storage】

Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from water. Corrosives area. Do not store in metal containers.
【Handling】

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale.
Hazards IdentificationBack to Contents
【Ingestion】

Causes gastrointestinal tract burns.
【Inhalation】

May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract.
【Skin】

Contact with skin causes irritation and possible burns, especially if the skin is wet or moist. Vesicant.
【Eyes】

May cause eye injury. Lachrymator. Causes eye irritation and burns.
【Hazards】

Contact with metals may evolve flammable hydrogen gas.
【EC Risk Phrase】

R 34 37
【EC Safety Phrase】

S 26 28 36/37/39 45
【UN (DOT)】

1759
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
【Respirators】

Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.
【Poison Class】

2
Fire Fighting MeasuresBack to Contents
【Flash Point】

114
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Do NOT use water directly on fire. Use carbon dioxide or dry chemical.
【Fire Potential】

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Clean up spills immediately, using the appropriate protective equipment. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal.
Stability and ReactivityBack to Contents
【Disposal Code】

11
【Stability】

Stable under normal temperatures and pressures.
【Incompatibilities】

Strong oxidizers. Water hydrolyzes material liberating acidic gas which in contact with metal surfaces can generate flammable and/or explosive hydrogen gas.
【Decomposition】

Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, sulfur oxides (SOx), including sulfur oxide and sulfur dioxide.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

1759
【Hazard Class】

8
【Packing Group】

I; II; III
【HS Code】

2904 90 20
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