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Hexahydrotoluene(108-87-2)

Hexahydrotoluene(108-87-2)
Product IdentificationBack to Contents
【Product Name】

Hexahydrotoluene
【Synonyms】

1H-Tetrazol-5-amine
1H-Tetrazol-5-ylamine
2H-Tetrazol-5-amine monohydrate
5-Amino-1,2,3,4-tetrazole
5-Amino-1H-tetrazole
5-Aminotetrazole
Thiolite HAT 1
【CAS】

4418-61-5
【CAS】

15454-54-3
【Formula】

CH3N5
【Formula】

CH5N5O
【Molecular Weight】

103.08
【EINECS】

224-581-7
【RTECS】

XF7465000
【RTECS Class】

Other
【Beilstein/Gmelin】

108872
【Beilstein Reference】

4-26-00-03469
Physical and Chemical PropertiesBack to Contents
【Appearance】

White crystals.
【Solubility in water】

Very soluble
【Melting Point】

216 - 217
【Boiling Point】

387
【Density】

1.51 g/cm3
【pKa/pKb】

6.00 (pKa)
【Partition Coefficient】

-.32
【Heat Of Vaporization】

116.0 kJ/mol
【Heat Of Combustion】

-1030 kJ/mol
【Usage】

Explosive.
First Aid MeasuresBack to Contents
【Ingestion】

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Ingestion】

Seek medical assistance.
【Inhalation】

Move victim to fresh air. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Inhalation】

May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
【Skin】

May cause skin irritation. The toxicological properties of this material have not been fully investigated.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Skin】

Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush with running water for at least 20 minutes. Wash skin with soap and water.
【Eyes】

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
【Eyes】

In case of contact with substance, immediately flush with running water for at least 20 minutes.
【Eyes】

May cause eye irritation. The toxicological properties of this material have not been fully investigated.
Handling and StorageBack to Contents
【Storage】

Keep container closed when not in use. Store in a tightly closed container. Keep container closed to prevent drying out. Material can explode if dry.
【Handling】

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Do not use if the material has evaporated to dryness.
Hazards IdentificationBack to Contents
【Ingestion】

May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
【Eyes】

See Skin.
【EC Risk Phrase】

R 4 11 36/37/38
【EC Safety Phrase】

S 16 26 36
【UN (DOT)】

1325
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Personal Protection】

Wear appropriate protective gloves, clothing and goggles.
【Respirators】

Wear positive pressure self-contained breathing apparatus (SCBA).
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Fire Fighting MeasuresBack to Contents
【Fire Fighting】

Small Fires: Dry chemical, carbon dioxide, sand, earth, water spray or regular foam. Large Fires: Water spray, fog or regular foam.
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. This material poses an explosion hazard when dry. Containers may explode when heated. May form very sensitive, explosive metallic compounds. Extinguishing media: Use agent most appropriate to extinguish fire. Cool containers with flooding quantities of water until well after fire is out. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
【Fire Potential】

Flammable/combustible material. May be ignited by friction, heat, sparks or flames.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Remove all sources of ignition. Use a spark-proof tool. If the material is dry, explosives experts may be necessary to dispose of the spill. Provide ventilation.
【Small spills/leaks】

Make no contact with the spilled material. ELIMINATE all ignition sources and ground all equipment. With clean shovel place material into clean, dry container and cover loosely; move containers from spill area.
Stability and ReactivityBack to Contents
【Incompatibilities】

Oxidizing agents.
【Stability】

Stable under normal temperatures and pressures.
【Decomposition】

Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
【Combustion Products】

Fire may produce irritating and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

1325
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