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Aluminum phosphide

CAS No.20859-73-8
Chemical Name:Aluminum phosphide
Synonyms:Detia;al-phos;Celphos;delicia;gastion;Talunex;celphine;celphide;Chelphos;fumitoxin
CBNumber:CB5319619
Molecular Formula:AlP
Formula Weight:57.96
MOL File:20859-73-8.mol
Aluminum phosphide Property
mp : 2000℃
density : 2.42
Stability:: Flammable solid. Contact with acids liberates highly toxic gas (phosphine). Incompatible with acids, moisture, oxidizing agents.
CAS DataBase Reference: 20859-73-8(CAS DataBase Reference)
NIST Chemistry Reference: Aluminum monophosphide(20859-73-8)
EPA Substance Registry System: Aluminum phosphide (AlP)(20859-73-8)
Safety
Hazard Codes : F,T+,N
Risk Statements : 15/29-28-32-50
Safety Statements : 3/9/14-30-36/37-45-61
RIDADR : 1397
HazardClass : 4.3
PackingGroup : I
Hazardous Substances Data: 20859-73-8(Hazardous Substances Data)

Aluminum phosphide Chemical Properties,Usage,Production

Chemical Properties
yellow or grey crystals
General Description
Aluminum phosphide is a dark gray or dry, yellow, crystalline solid. Aluminum phosphide reacts with moisture to give phosphine, a flammable and poisonous gas. Normally, phosphine will spontaneously ignite upon contact with air. If there is an excess of water, the phosphine fire will not normally ignite any surrounding combustible material.
Air & Water Reactions
Decomposed by water or moist air, evolving phosphine, a toxic gas that often ignites [Merck 11th ed. 1989].
Reactivity Profile
Aluminum phosphide is a reducing agent. Contact with mineral acids causes explosive evolution of toxic phosphine [Wang, C. C. et al., J. Inorg. Nucl. Chem., 1963, 25, p. 327]. Heating produces highly toxic fumes of phosphorus oxides. Can react vigorously upon contact with oxidizing agents. [Sax, 9th ed., p. 119].
Health Hazard
Acute toxicity occurs primarily by the inhalation route when Aluminum phosphide decomposes into the toxic gas, phosphine. The human median lethal dose for Aluminum phosphide has been reported to be 20 mg/kg. Rated as super toxic: probable oral lethal dose is less than 5 mg/kg or less than 7 drops for a 70 kg (150 lb.) person.
Fire Hazard
Releases toxic fumes on exposure to moist air, water, or acids. Decomposes to produce phosphine gas. Avoid water, dilute mineral acids, dilute or concentrated hydrochloric acid. Stable when dry. Avoid moist air.
Aluminum phosphide Preparation Products And Raw materials
Raw materials
Aluminium Phosphorus AMMONIUM CARBAMATE
Preparation Products
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20859-73-8(Aluminum phosphide)Related Search:
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