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Carbon disulphide

CAS No.75-15-0
Chemical Name:Carbon disulphide
Synonyms:CS2;CLSTN2;Weeviltox;NCI-C04591;caswellno162;Calsyntenin-2;Carbon sulfide;carbonsulphide;Kohlendisulfid;Alcadein-gamma
CBNumber:CB6279761
Molecular Formula:CS2
Formula Weight:76.14
MOL File:75-15-0.mol
Carbon disulphide Property
mp : -112--111 °C(lit.)
bp : 46 °C(lit.)
density : 1.266 g/mL at 25 °C
vapor density : 2.67 (vs air)
vapor pressure : 5.83 psi ( 20 °C)
refractive index : n20/D 1.627(lit.)
Fp : −29 °F
storage temp. : 2-8°C
color : ≤10(APHA)
Water Solubility : 2.9 g/L (20 ºC)
FreezingPoint : -110.3℃
Merck : 14,1811
Stability:: Stable. Extremely flammable. Highly volatile. Note low flash point and very wide explosion limits. Protect from heat, friction, shock, sunlight. Reacts violently with fluorine, azide solutions, zinc dust, liquid chlorine in the presence of iron. Incompatible with strong oxidizing agents, azides, aluminium, zinc, most common met
CAS DataBase Reference: 75-15-0(CAS DataBase Reference)
NIST Chemistry Reference: Carbon disulfide(75-15-0)
EPA Substance Registry System: Carbon disulfide(75-15-0)
Safety
Hazard Codes : F,T
Risk Statements : 11-36/38-48/23-62-63-39/23/24/25-23/24/25-48/20-40-36/37/38-19
Safety Statements : 16-33-36/37-45-7-26
RIDADR : UN 1131 3/PG 1
WGK Germany : 2
RTECS : FF6650000
HazardClass : 3
PackingGroup : I
Hazardous Substances Data: 75-15-0(Hazardous Substances Data)

Carbon disulphide Chemical Properties,Usage,Production

Chemical Properties
colourless to light yellow liquid with an unpleasant odour
Usage
Suitable for industrial hygiene analysis
General Description
A clear colorless to light yellow volatile liquid with a strong disagreeable odor. Boiling point 46° C. Flash point -22°F. Flammable over a wide vapor/air concentration range(1%-50%). Vapors are readily ignited; the heat of a common light bulb may suffice. Insoluble in water and more dense (10.5 lb / gal) than water. Hence sinks in water. Vapors are heavier than air. Used in the manufacture of rayon and cellophane, in the manufacture of flotation agents and as a solvent.
Air & Water Reactions
Highly flammable. Insoluble in water.
Reactivity Profile
Carbon disulphide has an extremely low autoignition temperature (125°C). May ignite or even explode when heated. The vapor or liquid has been known to ignite on contact with steam pipes, particularly if rusted [Anon., J. Roy. Inst. Chem., 1956, 80, p.664]. Explosion hazard when exposed to flame, heat, sparks or friction. Mixtures with lithium, sodium, potassium or dinitrogen tetraoxide may detonate when shocked. Potentially explosive reaction with nitrogen oxide, chlorine, permanganic acid(strong oxidizing agents). Vapor ignites in contact with aluminum powder or fluorine. Reacts violently with azides, ethylamine ethylenediamine, ethylene imine. Emits highly toxic fumes of oxides of sulfur when heated to decomposition [Bretherick, 5th ed., 1995, p. 663]. Sodium amide forms toxic and flammable H2S gas with CS2. (714)
Health Hazard
The material affects the central nervous system, cardiovascular system, eyes, kidneys, liver, and skin. It may be absorbed through the skin as a vapor or liquid, inhaled or ingested. The probable oral lethal dose for a human is between 0.5 and 5 g/kg or between 1 ounce and 1 pint (or 1 pound) for a 70 kg (150 lb.) person. In chronic exposures, the central nervous system is damaged and results in the disturbance of vision and sensory changes as the most common early symptoms. Lowest lethal dose for humans has been reported at 14 mg/kg or 0.98 grams for a 70 kg person. Alcoholics and those suffering from neuropsychic trouble are at special risk.
Fire Hazard
Ignition temperature dangerously low: 212F. Vapors may be ignited by contact with ordinary light bulb, when heated to decomposition, Carbon disulphide emits highly toxic fumes of oxides of sulfur. When heated to decomposition, emits highly toxic fumes of sulfur oxides and can react vigorously with oxidizing materials. Avoid air, rust, halogens, metal azides, metals, oxidants; when exposed to heat or flame reacts violently with aluminum, chlorine, azides, hypochlorite, ethylamine diamine, ethylene imine, fluorine, metallic azides of lithium, potassium, cesium, rubidium and sodium, nitrogen oxides, potassium, zinc and (sulfuric acid plus permanganate). Decomposes on standing for a long time.
Carbon disulphide Preparation Products And Raw materials
Raw materials
HYDROGEN SULFIDE Sulfur montmorillonite K 10 Silica gel Carbon Black Sulphur light disel oil
Preparation Products
Disulfiram ETHYLENE TRITHIOCARBONATE Aethoxidum Bis(pentamethylene)thiuram tetrasulfide 4,4'-Diacetylbiphenyl 1,3-DITHIOLE-2-THIONE Calcium thiocyanate Triallate Sodium dimethyldithiocarbamate 3-Chloro-4-fluoroacetophenone N,N'-Diethylthiourea CHLOROMETHIURON Proxan sodium Sodium O-butyldithiocarbonate 5-(4-METHOXYPHENYL)-1 3 4-OXADIAZOLE-2-& Potassium isobutylxanthate DIETHYLAMMONIUM DIETHYLDITHIOCARBAMATE 1-[2-(Dimethylamino)ethyl]-1H-tetrazole-5-thiol N,N-DIMETHYLDITHIOCARBAMIC ACID 1,4-PHENYLENE DIISOTHIOCYANATE 1H-BENZOIMIDAZOLE-2-THIOL Sodium isoamylxanthate S,S'-Dimethyl dithiocarbonate ROTENONE 4-Bromomandelic acid 5-(4-METHYLPHENYL)-1,3,4-OXADIAZOLE-2-THIOL Ethyl vinyl ketone Perchloromethylmercaptan 5-CHLORO-2-FLUOROPHENYL ISOTHIOCYANATE (2,5-Dimethoxyphenyl)acetic acid ETHYLEN-BIS-(4,6-DIMETHYL-TETRAHYDRO-1,3,5-THIADIAZIN-2-THION) 5-Mercapto-1-methyltetrazole 2-HEXANOYLFURAN 2-MERCAPTO-5-NITROBENZIMIDAZOLE N-Methyl-1-(methylthio)-2-nitroethylen-1-amine Sodium O-isobutyl dithiocarbonate 4-Chloromandelic acid 4'-Hydroxypropiophenone 3-CHLORO-4-FLUOROPHENYL ISOTHIOCYANATE AMYLXANTHIC ACID POTASSIUM SALT
Carbon disulphide Suppliers      Global( 149)Suppliers     
SupplierTelFaxEmailCountryProdListAdvantage
Shanghai Aladdin Bio-Chem Technology Co.,LTD 021-20337333/400-620-6333021-50323701sale@aladdin-e.comCHINA 24330 65
Shanghai Macklin Biochemical Co.,Ltd. 021-51821861021-51821727sales@macklin.cnCHINA 9960 55
J & K SCIENTIFIC LTD. ----jkinfo@jkchemical.com;market3@jkchemical.comCHINA 96847 76
Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-59487313(Beijing)+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing)sh@meryer.comCHINA 40407 62
Alfa Aesar 400-610-6006; 021-67582000021-67582001/03/05saleschina@alfa-asia.comCHINA 30333 84
Beijing dtftchem Technology Co., Ltd. 13651141086; 86(10)60275028、6027582086 (10) 60270825dtftchem@sina.comCHINA 4703 62
Energy Chemical 021-58432009 / 400-005-6266021-58436166-800info@energy-chemical.comCHINA 44198 61
Beijing Ouhe Technology Co., Ltd +86-10-4006331231;+86-10-51280831;+86-10-82967028+86-10-82967029sales@ouhechem.comCHINA 10815 60
JinYan Chemicals(ShangHai) Co.,Ltd. 13817811078,021-5042603086-021-50426522,50426273sales@jingyan-chemical.comCHINA 10108 60
Adamas Reagent, Ltd. 400-600-9262021-51701678mc@titansci.comCHINA 13697 59
 
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