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ジエチル亜鉛 (約1mol/Lヘキサン溶液)

CAS番号.557-20-0
化学名:ジエチル亜鉛 (約1mol/Lヘキサン溶液)
别名:ジエチル亜鉛 (約1mol/Lヘキサン溶液);ジエチル亜鉛;亜鉛ジエチル;ジエチル亜鉛,N-ヘキサン溶液;ジエチル亜鉛 (約15%トルエン溶液, 約1mol/L);ジエチル亜鉛 (約17%ヘキサン溶液, 約1mol/L)
英語化学名:Diethylzinc
英語别名:DEZ;DEZn;Et2Zn;CHEMR23;(C2H5)2Zn;ZINC ETHYL;Zinc ethide;ZINCDIETHYL;diethylzine;diethyl-zin
CBNumber:CB7149427
分子式:C4H10Zn
分子量:123.51
MOL File:557-20-0.mol
ジエチル亜鉛 (約1mol/Lヘキサン溶液) 物理性質
融点 : −28 °C(lit.)
沸点 : 98 °C
比重(密度) : 1.205 g/mL at 25 °C(lit.)
屈折率 : n20/D 1.498(lit.)
闪点 : 45 °F
貯蔵温度 : 0-6°C
水溶解度 : REACTS VIOLENTLY
Sensitive : Air & Moisture Sensitive
Merck : 14,3131
CAS データベース: 557-20-0(CAS DataBase Reference)
NISTの化学物質情報: Diethylzinc(557-20-0)
EPAの化学物質情報: Zinc, diethyl-(557-20-0)
安全性情報
主な危険性 : F,Xn,N,C
Rフレーズ : 14-17-34-50/53-67-65-62-48/20-11-51/53-14/15-63
Sフレーズ : 26-45-61-62-8-36/37/39-16-60-43
RIDADR : UN 3399 4.3/PG 1
WGK Germany : 2
RTECS 番号: ZH2077777
F : 10-23
TSCA : Yes
国連危険物分類 : 4.3
容器等級 : I
有毒物質データの: 557-20-0(Hazardous Substances Data)

ジエチル亜鉛 (約1mol/Lヘキサン溶液) MSDS


Diethylzinc

ジエチル亜鉛 (約1mol/Lヘキサン溶液) 化学特性,用途語,生産方法

化学的特性
Clear colorless solution
一般的な説明
Diethylzinc is a pyrophoric liquid with a garlic-like odor. Diethylzinc is stable when Diethylzinc is shipped in sealed tubes with carbon dioxide. Diethylzinc may decompose violently in water and ignite spontaneously with air. Diethylzinc is toxic by ingestion. If exposed to heat or flame, containers of Diethylzinc may explode. Diethylzinc is used as an aircraft fuel.
空気と水の反応
Highly flammable. Ignites in air with a blue flame giving off a peculiar garlic-like odor, [Merck, 11th ed., 1989]. Diethyl zinc is spontaneously flammable in air, [Douda(1966)]. Reacts violently with water to form flammable ethane gas, [Brauer(1965)].
反応プロフィール
Diethylzinc is pyrophoric in air, Diethylzinc ignites instantaneously. Diethylzinc reacts explosively with alcohols (methanol, ethanol), bromine, chlorine or liquefied sulfur dioxide [Houben-Weyl, 1973, 13.2a, p. 855, 757, 709]. Reaction with water, nitro compounds, arsenic trichloride, phosphorus trichloride is violent [Bretherick, 5th ed., 1995, p. 587].
健康ハザード
Inhalation of mist or vapor causes immediate irritation of nose and throat; excessive or prolonged inhalation of fumes from ignition or decomposition may cause ``metal fume fever'' (sore throat, headache, fever, chills, nausea, vomiting, muscular aches, perspiration, constricting sensation in lungs, weakness, sometimes prostration); symptoms usually last 12-24 hrs., with complete recovery in 24-48 hrs. Eyes are immediately and severely irritated on contact with liquid, vapor, or dilute solution; without thorough irrigation, cornea may be permanently damaged. Moisture in skin combines with chemical to cause thermal and acid burns; tissue may be scarred without prompt treatment. Ingestion is unlikely but would cause immediate burns at site of contact; pain, nausea, vomiting, cramps, and diarrhea may follow; if untreated, tissue may become ulcerated.
ジエチル亜鉛 (約1mol/Lヘキサン溶液) 上流と下流の製品情報
原材料
トリエチルアルミニウム (15%トルエン溶液, 約1.1mol/L) 塩化亜鉛
準備製品
ジエチル亜鉛 (約1mol/Lヘキサン溶液) 生産企業      Global( 104)Suppliers     
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J & K SCIENTIFIC LTD. ----jkinfo@jkchemical.com;market3@jkchemical.comCHINA 96847 76
Infinity SCI 400-106-2016 sales@infsci.comCHINA 6223 55
Shanghai Heng Yue Chemical Technology Co., Ltd. +86-021-51691771+86-021-58619266sales@hyscientific.comCHINA 229 56
Adamas Reagent, Ltd. 400-600-9262021-51701678mc@titansci.comCHINA 13697 59
Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-59487313(Beijing)+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing)sh@meryer.comCHINA 40407 62
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557-20-0(ジエチル亜鉛 (約1mol/Lヘキサン溶液)) キーワード:
ジプロピル亜鉛 ジブチル亜鉛 ジエチル亜鉛 (約1mol/Lヘキサン溶液) 2,6-ジエチルアニリン ジエチルベンゼン ジエチルエーテル (無水) ジエチルアルミニウムクロリド (約15%ヘキサン溶液, 約0.87mol/L) ジエチレントリアミン N,N-ジエチルホルムアミド 2-エチルアニリン 2-(2-アミノエチルアミノ)エタノール N,N-ジエチルアニリン N,N-ジイソプロピルエチルアミン (約10% N,N-ジメチルホルムアミド溶液) 2-ジエチルアミノエタノール 1,3-ジエチル-2-チオ尿素
557-20-0 (C2H5)2Zn diethyl-zin diethylzine ZINCDIETHYL Zinc ethide ZINC ETHYL DIETHYLZINC DIETHYLZINC, CYLINDER WITH 100 G DIETHYLZINC SOLUTION, IN TOLUENE (1.1 M) DIETHYLZINC, 15 WT. % (1.1M) SOLUTION IN TOLUENE DIETHYLZINC SOLUTION, ~1 M SOLUTION IN H EXANE DIETHYLZINC, 52.0 WT.% ZN (MINIMUM) DIETHYLZINC, FOR CAMBRIDGE NANOTECH INC DIETHYLZINC, 1.0M SOLUTION IN HEXANES DIETHYLZINC, 1.0M SOLUTION IN HEPTANE Diethylene Zinc DEZn Diethylzinc, 1.5M solution in toluene Diethylzinc, 1M solution in hexane Diethylzinc,elec.gr.(99.999%-Zn)PURATREM Diethylzinc,min.95% Diethylzinc,min.95%(10wt%inhexane)(Sure/Sealbottle) diethylzinc solution DIETHYLZINC , 10% IN HEXANE Diethylzinc, nominally 15% w/w in hexane, packaged under Argon in resealable ChemSealTM bottles Diethylzinc, nominally 15% w/w in hexane Diethylzinc (ca. 1mol/L in Hexane) DIETHYLZINC, 1M in heptane Diethylzinc, nominally 15% w/w in hexane, packaged under Argon in resealable ChemSeal bottles Benzenepropanoic acid, a,4-dichloro-, methyl ester ジエチル亜鉛 (約1mol/Lヘキサン溶液) ジエチル亜鉛 亜鉛ジエチル ジエチル亜鉛,N-ヘキサン溶液 ジエチル亜鉛 (約15%トルエン溶液, 約1mol/L) ジエチル亜鉛 (約17%ヘキサン溶液, 約1mol/L) 構造分類 金属別化合物 遷移金属化合物 亜鉛化合物
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