Phosphorus oxychloride

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Products Intro: Product Name:Phosphorus oxychloride
CAS:10025-87-3
Purity:98% Package:500Ml
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Products Intro: Product Name:Phosphorus oxychloride
CAS:10025-87-3
Purity:99%
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Products Intro: Product Name:Phosphorus oxychloride
CAS:10025-87-3
Purity:99%
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Products Intro: Product Name:Phosphorus(V) oxychloride, 99.999% (Metals basis)
CAS:10025-87-3
Package:5g Remarks:011847
Phosphorus oxychloride Basic information
Product Name:Phosphorus oxychloride
Synonyms:Fosforoxychlorid;OPCl3;Oxychlorid fosforecny;oxychloridfosforecny;Phosphoroxidchlorid;Phosphortrichloridoxid;Phosphorus chloride oxide (POCl3);Phosphorus oxytrichloride
CAS:10025-87-3
MF:Cl3OP
MW:153.33
EINECS:233-046-7
Product Categories:Inorganics;metal oxyhalide
Mol File:10025-87-3.mol
Phosphorus oxychloride Structure
Phosphorus oxychloride Chemical Properties
mp 1.25 °C(lit.)
bp 107 °C
density 1.675 g/mL at 20 °C(lit.)
vapor density 5.3 (vs air)
vapor pressure 104 mm Hg ( 50 °C)
refractive index n20/D 1.461
Fp 105.8°C
Water Solubility reacts exothermically
Sensitive Moisture Sensitive
Merck 14,7349
Stability:Stable. Reacts violently with water. Incompatible with many metals, alcohols, amines, phenol, DMSO, strong bases.
CAS DataBase Reference10025-87-3(CAS DataBase Reference)
NIST Chemistry ReferencePhosphoryl chloride(10025-87-3)
EPA Substance Registry SystemPhosphoric trichloride(10025-87-3)
Safety Information
Hazard Codes T+,C
Risk Statements 14-22-26-29-35-48/23-25
Safety Statements 26-45-7/8-36/37/39
RIDADR UN 1810 8/PG 2
WGK Germany 1
RTECS TH4897000
19-21
HazardClass 8
PackingGroup II
Hazardous Substances Data10025-87-3(Hazardous Substances Data)
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Phosphorus oxychloride Usage And Synthesis
Chemical Propertiescolourless liquid
General DescriptionA colorless fuming liquid with a pungent odor. Density 14.0 lb / gal. Very toxic by inhalation and corrosive to metals and tissue. Used in gasoline additives and hydraulic fluids.
Reactivity ProfilePhosphorus oxychloride is water reactive. Incompatible with strong oxidizing agents, alcohols, bases (including amines). May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291]. Combining the chloride with zinc dust caused immediate ignition, due to the formation of phosphine gas which ignites, [Mellor, 1940, Vol. 8, 1025]. An exotherm starting with the mixing of Phosphorus oxychloride with acetone (a ketone) lead to an explosion, may behave similarly with other ketones, [Organic Process Research and Development, Vol.4, No. 6,200, "Phosphorus oxychloride and Acetone: An Incompatibility Investigation Using ARC."]
Health HazardHealth Hazards : This poison is toxic by inhalation and ingestion and is strongly irritating to skin and tissues. It causes burns of the mucous membranes of the mouth and digestive tractand may be fatal.
Fire HazardPoisonous, corrosive, and irritating gases are generated when Phosphorus oxychloride is heated or is in contact with water. Phosphorus oxychloride may ignite other combustible materials (wood, paper, oil, etc.). Phosphorus oxychloride reacts violently with water. When heated to decomposition, Phosphorus oxychloride emits toxic fumes of chlorides and oxides of phosphorus; Phosphorus oxychloride will react with water or steam to produce heat and toxic and corrosive fumes. Incompatible with carbon disulfide; N,N-dimethylformamide; 2,5-dimethylpyrrole; 2,6-dimethyl- pyridine N-oxide; dimethylsulfoxide; Ferrocene-1,1-dicarboxylic acid; water; and zinc. Do not store with combustible materials, particularly fibrous organic materials, or with electrical or other equipment that can be corroded. Reacts violently with moisture.
Phosphorus oxychloride Preparation Products And Raw materials
Preparation Products4-(4-(BIS-(2-CHLOROETHYL)AMINO)BENZYLIDENE-2-PHENYL-OXAZOLINE-5-ONE-->Basic Blue 7-->6-CHLORO-5-CYANO-4-METHOXYMETHYL-3-NITRO-2-PICOLINE-->2-Chloro-3',4'-dihydroxyacetophenone-->DISTARCH PHOSPHATE-->2,6-Dichloro-4,8-dipiperidinopyrimidino[5,4-d]pyrimidine-->4-(Dimethylamino)benzophenone-->4-TRIFLUOROMETHYLBENZYLSULFONYL CHLORIDE-->5-METHYL-2-METHYLSULFANYL-PYRIMIDINE-->2-Chloro-5-thiophenecarboxaldehyde-->CHROMONE-3-CARBOXALDEHYDE-->6-N-HEXYLAMINOPURINE-->2,4-Dichloro-5-nitropyrimidine-->2-CHLORO-4-METHYLQUINOLINE-3-CARBONITRILE-->Quinazoline, 2-methyl- (6CI,7CI,8CI,9CI)-->PYRIDINE-3-SULFONYL CHLORIDE-->2,4,6-Trichloropyridine-->2,2'-BITHIOPHENE-5-CARBOXALDEHYDE-->Thieno[3,2-d]pyrimidine, 2,4-dichloro--->2-Chloro-4-methylpyrimidine-->P-TOLYL-ACETYL CHLORIDE-->2-ETHOXY-1-NAPHTHALDEHYDE-->Tris(2-ethylhexyl) phosphate-->DICAPTHON-->Starch, hydrogen phosphate, 2-hydroxypropyl ether-->Acetylated Dishtarch Phosphate-->Niclosamide-->3-CHLORO-1H-INDAZOLE-->Chloroambucil -->2,4-DICHLOROTHIENO[3,2-D]PYRIMIDINE-->2-Trifluoromethylbenzylsulfonyl chloride-->HEXAFLUOROGLUTARIC ANHYDRIDE-->4-Chloro-7-azaindole-->2-(Chloromethyl)-5-propoxypyridine-->SALICYLIC ACID 4-TERT-BUTYLPHENYL ESTER-->BENZALDEHYDE NITROGEN MUSTARD-->2-CHLOROLEPIDINE-->4,6-Dichloro-5-methoxypyrimidine-->4-Chloro-3,5-dinitrobenzaldehyde-->Disodium 4-nitrophenylphosphate
Raw materialsChlorine-->Phosphorus trichloride-->Phosphorus pentachloride-->Oxygen-->Sulfur dioxide-->Silicon dioxide-->White phosphorus-->Distillation equipment
Tag:Phosphorus oxychloride(10025-87-3) Related Product Information
Phosphorus trichloride Phosphorus pentoxide Calcium chloride Sulfuryl chloride Phosphorus oxychloride Diphosphoryl chloride Ammonium chloride Polyvinyl chloride phosphoric acid Methanesulfonyl chloride Potassium chloride Thionyl chloride Acrylyl chloride Dimethyl chlorothiophosphate CHLORIDE STANDARD Phosphorus 4-(DICYANOMETHYLENE)-2-METHYL-6-(JULOLIDIN-4-YL-VINYL)-4H-PYRAN Phosphorous acid