Methyl acrylate

Methyl acrylate Property

mp : -75 °C bp : 80 °C(lit.) density : 0.956 g/mL at 25 °C(lit.) vapor density : 3 (vs air) vapor pressure : 67.5 mm Hg ( 20 °C) refractive index : n20/D 1.402(lit.) Fp : 26.6 °F storage temp. : Refrigerator (+4°C) + Flammables area Water Solubility : 60 g/L (20 ºC) Merck : 14,6011 BRN : 605396 Stability:: Stable. Incompatible with bases, acids, oxidizing agents, peroxides. May polymerize on exposure to light. Highly flammable. Commercial product may be inhibited by the presence of hydroquinone monomethyl ether. CAS DataBase Reference: 96-33-3(CAS DataBase Reference) NIST Chemistry Reference: 2-Propenoic acid, methyl ester(96-33-3) EPA Substance Registry System: 2-Propenoic acid, methyl ester(96-33-3)

Safety

Hazard Codes : F,Xn Risk Statements : 11-20/21/22-36/37/38-43 Safety Statements : 9-25-26-33-36/37-43-43A RIDADR : UN 1919 3/PG 2 WGK Germany : 2 RTECS : AT2800000 F : 8 HazardClass : 3 PackingGroup : II Hazardous Substances Data: 96-33-3(Hazardous Substances Data)

Methyl acrylate Chemical Properties,Usage,Production

Chemical Properties colourless liquid General Description Colorless volatile liquid with an acrid odor. Flash point 27°F. Vapors may irritate the eyes and respiratory system. Highly toxic by inhalation, ingestion and skin absorption. Less dense than water (0.957 gm / cm3) and slightly soluble in water, hence floats on water. Vapors heavier than air. Air & Water Reactions Highly flammable. Forms peroxides when exposed to air that may initiate spontaneous, exothermic polymerization. Peroxide formation usually proceeds slowly. Slightly soluble in water. Reactivity Profile METHYL ACRYLATE ignites readily when exposed to heat, flame or sparks. Offers a dangerous fire and explosion hazard. Reacts vigorously with strong oxidizing materials. Forms peroxides when exposed to air that may initiate spontaneous exothermic polymerization. Peroxide formation usually proceeds slowly. Added inhibitor retards polymerization. If the inhibitor is consumed during long storage, explosive polymerization may occur [MCA Case History No. 2033]. Also subject to strongly exothermic polymerization if heated for prolonged periods or contaminated. Health Hazard May irritate skin, eyes, respiratory system, and gastro- intestinal tract. Fumes cause tears.

Methyl acrylate Preparation Products And Raw materials

Raw materials Acrolein Polyethylene-polypropylene glycol Maleic anhydride Acrylamide PASSION FLOWER OIL Castor oil Glycerol Acrylic acid Pentaerythritol Methanol 1,2-Propanediol Benzoic acid Carbomer 940 Fatty acids, C8-10, triesters with trimethylolpropane RAPESEED OIL Propylene oxide ketene

Preparation Products EPROSARTAN Adhesive for nonwoven fabric 1-Methyl-4-piperidinol hydrochloride Undecan-4-olide 2-Ethylhexyl acrylate laurylamide carboxyamine propionate JHZ-102 chelating resin containing acrylic acid amino acetic group Methyl 3-methylthiopropionate 2-Phosphonobutane-1,2,4-tricarboxylic acid efficient polymer catalyst for acrylation-synthesis and characterigation of polyamide containing supernucleophilic reagent oil-proof, water-proof finishing agent (E)-METHYL 3-(4-BROMOPHENYL)ACRYLATE 3-DIMETHYLAMINOPROPIONIC ACID REMIFENTANIL acrylate resin emulsion new type CSF series modified sacrylic binder METHYL 4-OXOTETRAHYDROTHIOPHENE-3-CARBOXYLATE 1,3-Dimethylpiperidin-4-one 4-Dodecanolide Nitrocellulose enamel 5-Chloro-2-methyl-4-isothiazolin-3-one AC anti-fungus leather finishing agent acrylate resin emulsion M-1 METHYL 4-(AMINOMETHYL)CYCLOHEXANECARBOXYLATE 1-Phenethyl-4-piperidone 3-dodecylaminopropionic acid warp dressing agent MVAc Leather coating agent of filling acrylic resin 4-Chloro-1-methylpiperidine hydrochloride AMBERLITE XAD-16 Methyl 1-methyl-4-oxopiperidine-3-carboxylate BT modified acrylic resin binder series laurylamide propionate JHZ-101 weather-proof acrylic binder series N-hydroxyethyl-N-hydroxyalkyl-β-alanine FEMA 2763 softener D3 acrylate resin emulsion s-1 Pioglitazone Disperse Brown 19

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