Phosphorous acid

Phosphorous acid Suppliers list
Company Name:J & K SCIENTIFIC LTD.  
Tel:400-666-7788 +86-10-82848833
Email:jkinfo@jkchemical.com;market3@jkchemical.com
Products Intro: Product Name:Phosphorous acid
CAS:13598-36-2
Purity:98% Package:1KG,500G
Company Name:Meryer (Shanghai) Chemical Technology Co., Ltd.  
Tel:+86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-59487313(Beijing)
Email:sh@meryer.com
Products Intro: Product Name:Phosphorous acid
CAS:13598-36-2
Purity:99% Package:500g Remarks:AAA125411
Company Name:Alfa Aesar  
Tel:400-610-6006; 021-67582000
Email:saleschina@alfa-asia.com
Products Intro: Product Name:Phosphorous acid, 98+%
CAS:13598-36-2
Package:250g Remarks:A11189
Company Name:BeiJing Hwrk Chemicals Limted  
Tel:4006990298 010-57411839 020-31335234 021-51691807
Email:sales@hwrkchemical.com
Products Intro: Product Name:Phosphorous acid
CAS:13598-36-2
Purity:99.00% Package:100g Remarks:100g, 260
Company Name:Energy Chemical  
Tel:021-58432009 / 400-005-6266
Email:info@energy-chemical.com
Products Intro: Product Name:Phosphorous acid
CAS:13598-36-2
Purity:98+% Package:1kg,250g,5kg
Phosphorous acid Basic information
Product Name:Phosphorous acid
Synonyms:dihydroxyphosphineoxide;orthophosphorus;Orthophosphorus acid;orthophosphorusacid;Phosphorous acid, ortho;Phosphorus trihydroxide;phosphorustrihydroxide;Trihydroxyphosphine
CAS:13598-36-2
MF:H3O3P
MW:82
EINECS:237-066-7
Product Categories:Inorganic Chemicals;Inorganics
Mol File:13598-36-2.mol
Phosphorous acid Structure
Phosphorous acid Chemical Properties
mp 73 °C
bp 200 °C
density 1.651 g/mL at 25 °C(lit.)
Fp 200°C
storage temp. 0-6°C
Water Solubility SOLUBLE
Sensitive Air Sensitive & Hygroscopic
Merck 14,7346
Stability:Stable. Incompatible with strong bases. Hygroscopic.
CAS DataBase Reference13598-36-2(CAS DataBase Reference)
NIST Chemistry Reference(HO)2HPO(13598-36-2)
EPA Substance Registry SystemPhosphonic acid(13598-36-2)
Safety Information
Hazard Codes C
Risk Statements 22-35
Safety Statements 26-36/37/39-45
RIDADR UN 2834 8/PG 3
WGK Germany 1
RTECS SZ6400000
3
HazardClass 8
PackingGroup III
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
Phosphorous acid Usage And Synthesis
Chemical Propertieswhite crystalline solid
General DescriptionA white or yellow crystalline solid (melting point 70.1 deg C) or a solution of the solid. Density 1.651 g /cm3 . Contact may severely irritate skin, eyes, and mucous membranes. Toxic by ingestion, inhalation and skin absorption.
Air & Water ReactionsDeliquescent. Absorbs oxygen from the air very readily to form phosphoric acid [Hawley]. Soluble in water.
Reactivity ProfilePhosphorous acid decomposes when heated to form phosphine, a gas that usually ignites spontaneously in air. Absorbs oxygen from the air to form phosphoric acid [Hawley]. Forms yellow deposits in aqueous solution that are spontaneously flammable upon drying. Reacts exothermically with chemical bases (for example: amines and inorganic hydroxides) to form salts. These reactions can generate dangerously large amounts of heat in small spaces. Dissolution in water or dilution of a concentrated solution with additional water may generate significant heat. Reacts in the presence of moisture with active metals, including such structural metals as aluminum and iron, to release hydrogen, a flammable gas. Can initiate the polymerization of certain alkenes. Reacts with cyanide compounds to release gaseous hydrogen cyanide. May generate flammable and/or toxic gases in contact with dithiocarbamates, isocyanates, mercaptans, nitrides, nitriles, sulfides, and strong reducing agents. Additional gas-generating reactions occur with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (to give SO2), and carbonates (to give CO2).
Health HazardTOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Fire HazardNon-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.
Tag:Phosphorous acid(13598-36-2) Related Product Information
Diphenylphosphoryl azide METHYLPHOSPHONIC ACID METHYLENEDIPHOSPHONIC ACID TRISODIUM SALT METHYLENEDIPHOSPHONIC ACID ACETYL PHOSPHATE LITHIUM POTASSIUM SALT DIETHYL 2-BROMOETHYLPHOSPHONATE PHENYL PHOSPHATE DISODIUM SALT Amino tris(methylene phosphonic acid) Tris(2-chloroethyl) phosphate Phosphorous acid Phosphorus Stearic acid Phosphinic acid Triphenyl phosphite Citric acid Phosphonic acid, disodium salt Folic acid Hyaluronic acid